Investigating the Impact of Three Recycling Cycles on the Thermal and Mechanical Properties of Composites Made from Aspen Wood Flour and Recycled Polyethylene for Packaging Applications

Document Type : Original Article

Authors
1 Associate professor, Department of Wood and Paper, Sava.C., Islamic Azad University, Savadkooh, Iran
2 Assistant professor, Department of Engineering Sciences, Technical and Vocational University (TVU), Tehran, Iran
Abstract
This article investigates the impact of recycling on the thermal and mechanical properties of composites made from ash wood flour and recycled polyethylene. Given the growing concerns about environmental pollution and the necessity of material reuse, this research analyzes the effects of recycling on the physical and functional characteristics of these composites in packaging applications. Samples were prepared with varying ratios of wood flour and polyethylene, and thermal properties such as glass transition temperature, along with mechanical properties including tensile strength and hardness, were measured. The results indicated that an increase in the number of recycling cycles negatively affected tensile strength, tensile and flexural elastic modulus, and impact resistance, showing reductions of 21.9%, 25.4%, 30.3%, 27.9%, and 23.1%, respectively. However, thermal stability remained relatively unchanged, with residual charcoal content measured at 9.96%, 9.36%, 8.16%, and 7.76%. This study could contribute to the development of environmentally friendly packaging materials and provide new opportunities for utilizing recycled materials in various industries. The findings underscore the need to balance the benefits of recycling with its negative impacts on mechanical properties, serving as a guide for designing sustainable packaging materials in the future.
Keywords
Subjects

اصل مقاله

[1] S. Pourabbasi and A. Samariha, "Evaluation of the physical and mechanical properties of polyethylene/corn stalk fiber composites used in the packaging industry," Packaging Sci. Art, vol. 15, no. 57, pp. 13–19, 2024. [Online]. Available: https://dor.isc.ac/dor/20.1001.1.22286675.1403.15.57.2.1 (in Persian)
[2] J. Ebrahimpour Kasmani and A. Samariha, "Investigating the characteristics of composite made of wood flour, recycled PVC and nano silica for packaging purposes," Packaging Sci. Art, vol. 15, no. 59, pp. 1–8, 2024. [Online]. Available: https://dor.isc.ac/dor/20.1001.1.22286675.1403.15.59.1.4 (in Persian)
[3] J. R. Jambeck et al., "Plastic waste inputs from land into the ocean," Science, vol. 347, no. 6223, pp. 768–771, 2015, doi: 10.1126/science.1260352.
[4] A. K. Singh, R. Bedi, and B. S. Kaith, "Composite materials based on recycled polyethylene terephthalate and their properties – A comprehensive review," Compos. B Eng., vol. 219, p. 108928, 2021, doi: 10.1016/j.compositesb.2021.108928.
[5] A. K. Bledzki and J. Gassan, "Composites reinforced with cellulose based fibres," Prog. Polym. Sci., vol. 24, no. 2, pp. 221–274, 1999, doi: 10.1016/S0079-6700(98)00018-5.
[6] J. Zhang, H. Wang, R. Ou, and Q. Wang, "The properties of flax fiber reinforced wood flour/high density polyethylene composites," J. Forestry Res., vol. 29, no. 2, pp. 533–540, 2018, doi: 10.1007/s11676-017-0461-0.
[7] M. Rabnawaz, I. Wyman, R. Auras, and S. Cheng, "A roadmap towards green packaging: the current status and future outlook for polyesters in the packaging industry," Green Chem., vol. 19, no. 20, pp. 4737–4753, 2017, doi: 10.1039/c7gc02521a.
[8] A. K. Mohanty, M. Misra, and L. T. Drzal, Eds., Natural fibers, biopolymers, and biocomposites. CRC Press, 2005, doi: 10.1201/9780203508206.
[9] R. C. Thompson et al., "Lost at sea: where is all the plastic?," Science, vol. 304, no. 5672, pp. 838–838, 2004, doi: 10.1126/science.1094559.
[10] J. Deng et al., "Overview of renewable polysaccharide-based composites for biodegradable food packaging applications," Green Chem., vol. 24, no. 2, pp. 480–492, 2022, doi: 10.1039/d1gc03898b.
[11] K. B. Adhikary, S. Pang, and M. P. Staiger, "Dimensional stability and mechanical behaviour of wood–plastic composites based on recycled and virgin high-density polyethylene (HDPE)," Compos. B Eng., vol. 39, no. 5, pp. 807–815, 2008, doi: 10.1016/j.compositesb.2007.10.005.
[12] O. Faruk, A. K. Bledzki, H. P. Fink, and M. Sain, "Biocomposites reinforced with natural fibers: 2000–2010," Prog. Polym. Sci., vol. 37, no. 11, pp. 1552–1596, 2012, doi: 10.1016/j.progpolymsci.2012.04.003.
[13] M. Sain and S. Panthapulakkal, "Bioprocess preparation of wheat straw fibers and their characterization," Ind. Crops Prod., vol. 23, no. 1, pp. 1–8, 2006, doi: 10.1016/j.indcrop.2005.01.006.
[14] Q. T. Shubhra, A. M. Alam, and M. A. Quaiyyum, "Mechanical properties of polypropylene composites: A review," J. Thermoplast. Compos. Mater., vol. 26, no. 3, pp. 362–391, 2013, doi: 10.1177/0892705711428659.
[15] M. Bengtsson, M. Le Baillif, and K. Oksman, "Extrusion and mechanical properties of highly filled cellulose fibre–polypropylene composites," Compos. A Appl. Sci. Manuf., vol. 38, no. 8, pp. 1922–1931, 2007, doi: 10.1016/j.compositesa.2007.03.004.
[16] S. K. Najafi, E. Hamidinia, and M. Tajvidi, "Mechanical properties of composites from sawdust and recycled plastics," J. Appl. Polym. Sci., vol. 100, no. 5, pp. 3641–3645, 2006, doi: 10.1002/app.23159.
[17] A. Karmarkar, S. S. Chauhan, J. M. Modak, and M. Chanda, "Mechanical properties of wood–fiber reinforced polypropylene composites: Effect of a novel compatibilizer with isocyanate functional group," Compos. A Appl. Sci. Manuf., vol. 38, no. 2, pp. 227–233, 2007, doi: 10.1016/j.compositesa.2006.05.005.
[18] M. G. Salemane, and A. S. Luyt,  Thermal and mechanical properties of polypropylene–wood powder composites. Journal of Applied Polymer Science, vol. 100, no. 5, 4173-4180, 2006, doi: https://doi: 10.1002/app.23521.
[19] G. Zhuo, X. Zhang, Y. Liu, and M. Wang, "Effect of multiple recycling on properties of poplar fiber reinforced high density polyethylene wood-plastic composites," Mater. Res. Express, vol. 6, no. 12, p. 125514, 2019, doi: 10.1088/2053-1591/ab5742.
[20] A. Delviawan, S. Suzuki, Y. Kojima, and H. Kobori, "The influence of filler characteristics on the physical and mechanical properties of wood plastic composite(s)," Rev. Agric. Sci., vol. 7, pp. 1–9, 2019, doi: 10.7831/ras.7.1.
[21] I. Turku, T. Kärki, and A. Puurtinen, "Flammability of wood plastic composites prepared from plastic waste," Fire Mater., vol. 42, no. 2, pp. 198–201, 2018, doi: 10.1002/fam.2480.
[22] E. Jayamani and V. Balakrishnan, "Thermal Properties and Flammability of Wood Plastic Composites," in Wood Polymer Composites: Recent Advancements and Applications, Singapore: Springer, 2021, pp. 161–178, doi: 10.1007/978-981-16-1606-8_8.
[23] Y. Guo, S. Zhu, Y. Chen, and D. Li, "Thermal properties of wood-plastic composites with different compositions," Materials, vol. 12, no. 6, p. 881, 2019, doi: 10.3390/ma12060881.
 
 
Volume 4, Issue 1 - Serial Number 7
August 2025
Pages 93-105

  • Receive Date 24 March 2025
  • Revise Date 15 May 2025
  • Accept Date 20 May 2025
  • First Publish Date 20 May 2025
  • Publish Date 22 June 2025